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Effect of 2-butenal manufacture wastewater to methanogenic activity and microbial community

Guangqing Song, Hongbo Xi, Xiumei Sun, Yudong Song, Yuexi Zhou

《环境科学与工程前沿（英文）》 2018年第12卷第5期 doi: 10.1007/s11783-018-1056-5

摘要：

The inhibition ratio sharply increased with the increasing COD.

The absorbance of UV-vis at 420 nm showed a linear correlation with the SMA.

The molecular structure of EPS has changed when COD was 9585 mg/L.

Illumina Miseq sequencing was employed to reveal the microbial composition.

关键词： 2-butenal manufacture wastewater Methanogenic activity Specific methanogenic activity (SMA) Extracellular polymeric substance (EPS) Microbial community

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Cytochrome P450 monooxygenase specific activity reduction in wheat

Kangxin HE,Qixing ZHOU

《环境科学与工程前沿（英文）》 2016年第10卷第2期页码 270-275 doi: 10.1007/s11783-015-0813-y

摘要： Roxithromycin, as widely used medicine and livestock growth promoter, arouses concern because its occurrence and persistence in soil environments. However, effects of roxithromycin in higher plants are still vague. Accordingly, we hypothesized that roxithromycin-contaminated soil may exhibits ecotoxicological effects in wheat ( ). In this study, effects induced by a gradient concentration of roxithromycin stress (0.01, 0.1, 1, 10, and 100 mg·kg ) was investigated in a 7-d soil test in . Results indicated that the specific activity of cytochrome P450 (CYP450) monooxygenase was decreased dramatically with the concentration of roxithromycin in soil. The IC value was 8.78 mg·kg of roxithromycin. On the contrary, the growth related endpoints (i.e., the germination percentage, the biomass and the height), the content related endpoints (i.e., soluble protein content and CYP450 content), and the superoxide dismutase (SOD) activity failed to reveal the roxithromycin-induced effects. Further analysis revealed that the CYP450 monooxygenase specific activity reduction was enzymatic mechanism mediated, other than oxidative stress induced. We conclude that the soil roxithromycin declined the CYP450 monooxygenase activity in by the inhibition of the enzymatic mechanism. Further efforts can include, but are not limited to, investigation of joint effects induced by combined exposure of roxithromycin and the pesticides and evaluation of the similar effects in other higher plants.

关键词： roxithromycin toxic effect cytochrome P450 monooxygenase soil environment Triticum aestivum biomarker

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Characterization of a phenanthrene-degrading methanogenic community

Quanhui Ye, Chengyue Liang, Chongyang Wang, Yun Wang, Hui Wang

《环境科学与工程前沿（英文）》 2018年第12卷第5期 doi: 10.1007/s11783-018-1083-2

摘要：

The mixed samples of contaminated soil, sludge and coke wastewater showed great phenanthrene methanogenic degradation potential.

Comamonadaceae, Nocardiaceae and Methanobacterium were dominant members.

Hexane, hexadecane and benzene could enhance phenanthrene degradation.

关键词： Phenanthrene degradation potential Methanogenic Bacterial population Archaeal group

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Acid resistance of methanogenic bacteria in a two-stage anaerobic process treating high concentration

ZHOU Xuefei, REN Nanqi

《环境科学与工程前沿（英文）》 2007年第1卷第1期页码 53-56 doi: 10.1007/s11783-007-0010-8

摘要： In this study, the two-stage upflow anaerobic sludge blanket (UASB) system and batch experiments were employed to evaluate the performance of anaerobic digestion for the treatment of high concentration methanol wastewater. The acid resistance of granular sludge and methanogenic bacteria and their metabolizing activity were investigated. The results show that the pH of the first UASB changed from 4.9 to 5.8 and 5.5 to 6.2 for the second reactor. Apparently, these were not the advisable pH levels that common methanogenic bacteria could accept. The methanogenic bacteria of the system, viz. Methanosarcina barkeri, had some acid resistance and could still degrade methanol at pH 5.0. If the methanogenic bacteria were trained further, their acid resistance would be improved somewhat. Granular sludge of the system could protect the methanogenic bacteria within its body against the impact of the acidic environment and make them degrade methanol at pH 4.5. The performance of granular sludge was attributed to its structure, bacteria species, and the distribution of bacterium inside the granule.

关键词： pH Granular upflow anaerobic advisable pH methanogenic

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Modeling of specific structure crystallization coupling with dissolution

Yuanhui JI, Hongliang QIAN, Chang LIU, Xiaohua LU, Xin FENG, Xiaoyan JI,

《化学科学与工程前沿（英文）》 2010年第4卷第1期页码 52-56 doi: 10.1007/s11705-009-0301-7

摘要： In this paper, the research framework for specific structure crystallization modeling has been proposed in which four steps are required in order to investigate the rigorous crystallization modeling by thermodynamics. The first is the activity coefficient model of the solution, the second is Solid-Liquid equilibrium, the third and fourth are the dissolution and crystallization kinetics modeling, respectively. Our investigations show that the mechanisms of complex structure formation and microphase transition can be analyzed by combining the dissolution and crystallization kinetics modeling. Moreover, the formation mechanism of the porous KCl has been analyzed, which may provide a reference for the porous structure formation in the advanced material synthesis.

关键词： structure crystallization activity coefficient reference KCl dissolution

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Preparation of D-lysine by chemical reaction and microbial asymmetric transformation

LIU Yi, JIAO Qingcai, YIN Xiaoxing

《化学科学与工程前沿（英文）》 2008年第2卷第1期页码 40-43 doi: 10.1007/s11705-008-0023-2

摘要： The DL-lysine crystals from the racemization of L-lysine was treated as substrate with AS1.1009 intact cells as biocatalysts to produce crystalline D-lysine with a yield of 56.6% from the reaction mixture after simple purification. In the presence of 0.10 molar equivalent of salicylaldehyde, L-lysine racemization can be completed within 4 h in 1.0 mol/L of NaOH at 100°C. The activation energy of the processes was 62187.86 J/mol. The characteristics of AS1.1009 decarboxylase were studied. Under the conditions of pH 8.0, temperature 37°C, cell concentration 10 g/L, tween-80 0.5 g/L, substrate concentration 30 g/L, and the specific activity of up to 3840 U, L-lysine can be completely degraded by the decarboxylase for 12 h under the optimal conditions.

关键词： substrate temperature specific activity presence decarboxylase

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Topology optimization and seismic collapse assessment of shape memory alloy (SMA)-braced frames: Effectiveness

Aydin HASSANZADEH; Saber MORADI

《结构与土木工程前沿（英文）》 2022年第16卷第3期页码 281-301 doi: 10.1007/s11709-022-0807-3

摘要： This paper presents a seismic topology optimization study of steel braced frames with shape memory alloy (SMA) braces. Optimal SMA-braced frames (SMA-BFs) with either Fe-based SMA or NiTi braces are determined in a performance-based seismic design context. The topology optimization is performed on 5- and 10-story SMA-BFs considering the placement, length, and cross-sectional area of SMA bracing members. Geometric, strength, and performance-based design constraints are considered in the optimization. The seismic response and collapse safety of topologically optimal SMA-BFs are assessed according to the FEMA P695 methodology. A comparative study on the optimal SMA-BFs is also presented in terms of total relative cost, collapse capacity, and peak and residual story drift. The results demonstrate that Fe-based SMA-BFs exhibit higher collapse capacity and more uniform distribution of lateral displacement over the frame height while being more cost-effective than NiTi braced frames. In addition to a lower unit price compared to NiTi, Fe-based SMAs reduce SMA material usage. In frames with Fe-based SMA braces, the SMA usage is reduced by up to 80%. The results highlight the need for using SMAs with larger recoverable strains.

关键词： topology optimization shape memory alloy Fe-based SMA steel braced frames performance-based seismic design collapse assessment

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METAGENOMICS COMBINED WITH HIGH-THROUGHPUT SEQUENCING REVEALS THE METHANOGENIC POTENTIAL OF FRESH CORN

《农业科学与工程前沿（英文）》 2023年第10卷第3期页码 403-423 doi: 10.15302/J-FASE-2022471

摘要：

● Methane production from fresh straw was 7.50% higher than dry straw.

关键词： fresh corn straw high solid anaerobic digestion metagenomics microbial communities thermophilic

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Experimental flexural behavior of SMA-FRP reinforced concrete beam

Adeel ZAFAR, Bassem ANDRAWES

《结构与土木工程前沿（英文）》 2013年第7卷第4期页码 341-355 doi: 10.1007/s11709-013-0221-y

摘要： The most critical drawback in currently used steel reinforcement in reinforced concrete (RC) structures is susceptibility to accumulation of plastic deformation under excessive loads. Many concrete structures due to damaged (yielded) steel reinforcement have undergone costly repairs and replacements. This research presents a new type of shape memory alloy (SMA)-based composite reinforcement with ability to withstand high elongation while exhibiting pseudo-elastic behavior. In this study, small diameter SMA wires are embedded in thermoset resin matrix with or without additional glass fibers to develop composite reinforcement. Manufacturing technique of new proposed composite is validated using microscopy images. The proposed SMA-FRP composite square rebars are first fabricated and then embedded in small scale concrete T-beam. 3-point bending test is conducted on manufactured RC beam using a cyclic displacement controlled regime until failure. It is found that the SMA-FRP composite reinforcement is able to enhance the performance of concrete member by providing re-centering and crack closing capability.

关键词： re-centering shape memory alloys concrete composite fiber reinforced polymer scanning electron microscopy

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Grafting of PEG400 onto the surface of LLDPE/SMA film

CHEN Gufeng, ZHANG Yi, XU Jiarui, ZHU Yafei

《化学科学与工程前沿（英文）》 2007年第1卷第2期页码 128-131 doi: 10.1007/s11705-007-0024-6

摘要： Linear low-density polyethylene (LLDPE) was melt and blended with styrene-maleic anhydride copolymer (SMA). The blending films were then immersed in poly(ethylene glycol)400 (PEG400) at room temperature. The surface composition of the blend films was determined by Fourier transform infra-red spectroscopy coupled with a variable incidence angle attenuated total reflection accessory (ATR-FTIR). Results show that PEG400 can be grafted onto the surface of the films via esterification with SMA. The immersion of PEG promotes the enrichment of SMA onto the surface of the films. The water contact angle data show that grafting of PEG400 onto PE can greatly improve the hydrophilicity of the PE surface. These experiments show that surface functionalization of polyethylene films by blending SMA and then surface grafting of PEG is feasible, which suggest an effective and simple route for PE surface modification via blending and grafting.

关键词： hydrophilicity temperature effective immersion reflection accessory

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Parametric study on damage control design of SMA dampers in frame-typed steel piers

Xiaoqun LUO, Hanbin GE, Tsutomu USAMI,

《结构与土木工程前沿（英文）》 2009年第3卷第4期页码 384-394 doi: 10.1007/s11709-009-0065-7

摘要： This paper focuses on damage control design of SMA dampers in steel frame piers. A parametric study based on time history analyses is carried out on frame-typed bridge piers with axial-type SMA damping device. The parameters examined are design parameters of strength ratio and stiffness ratio . Seismic performance indexes on displacement and strain are investigated under three JRA recommended Level 2 Ground Type П strong earthquake motions. Design recommendations are suggested following the results of the parametric study.

关键词： damage control design shape memory alloy parameter study displacement-based verification strain-based verification time history analysis

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福岛核事故后中国广东核电集团核电厂抗震设计和评估进展

毛庆,吴应喜,张健,孟阿军,张涛,杨春菊,刘芳

《中国工程科学》 2013年第15卷第4期页码 46-51

摘要：

本文介绍了核电站抗震设计要求、在建和运行核电站的抗震设计情况以及运行核电站遭遇地震灾害的情况，简述了福岛核事故后世界各国核电站在抗震方面采取的措施，针对中国广东核电集团在福岛核事故后的行动进行了详细介绍，并提出了新建核电厂在抗震设计和评估方面的策略，以期通过技术手段持续提升核电站的抗震能力。

关键词：抗震设计基准超设计基准地震抗震裕量分析（SMA）隔震

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Seismic responses and resilience of novel SMA-based self-centring eccentrically braced frames under near-fault

Zhi-Peng CHEN; Songye ZHU

《结构与土木工程前沿（英文）》 2022年第16卷第8期页码 962-975 doi: 10.1007/s11709-022-0873-6

摘要： In this paper, the seismic responses and resilience of a novel K-type superelastic shape memory alloy (SMA) self-centring (SC) eccentrically braced frame (EBF) are investigated. The simulation models of the SMA-based SC-EBF and a corresponding equal-stiffness traditional EBF counterpart are first established based on some existing tests. Then twenty-four near-fault ground motions are used to examine the seismic responses of both EBFs under design basis earthquake (DBE) and maximum considered earthquake (MCE) levels. Structural fragility and loss analyses are subsequently conducted through incremental dynamic analyses (IDA), and the resilience of the two EBFs are eventually estimated. The resilience assessment basically follows the framework proposed by Federal Emergency and Management Agency (FEMA) with the additional consideration of the maximum residual inter-storey drift ratio (MRIDR). The novel SMA-based SC-EBF shows a much better resilience in the study and represents a promising attractive alternative for future applications.

关键词： shape memory alloy eccentrically braced frame self-centring fragility loss function resilience

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Computational studies on the seismic response of the State Route 99 bridge in Seattle with SMA/ECC plastic

Jiping GE, M. Saiid SAIIDI, Sebastian VARELA

《结构与土木工程前沿（英文）》 2019年第13卷第1期页码 149-164 doi: 10.1007/s11709-018-0482-6

摘要： This paper reports a computational study on the seismic response of a three-span highway bridge system incorporating conventional and novel substructure details for improved seismic performance. The bridge has three continuous spans supported by two single-column piers and integral abutments founded on drilled shafts. It will be the first full-scale highway bridge to use superelastic shape memory alloy bars (SMA) and engineered cementitious composite (ECC) to mitigate column plastic hinge damage and minimize residual displacements after a strong earthquake. A three-dimensional computational model capturing the nonlinear constitutive response of the novel materials and the effects of dynamic soil-structure interaction was developed to assess the seismic response of the bridge in finite-element software OpenSees. Two versions of the same bridge were analyzed and compared, one with conventional cast-in-place reinforced concrete columns, and the other with top plastic hinges incorporating Nickel-Titanium (NiTi) SMA reinforcing bars and ECC. The novel SMA/ECC plastic hinges were found to substantially reduce damage and post-earthquake residual displacements in the bridge substructure, but led to larger maximum drifts relative to the bridge with conventional reinforced concrete plastic hinges. The analysis results suggested that the novel plastic hinges could lead to improved post-earthquake serviceability of bridges after intense earthquakes.

关键词： seismic design analytical simulation near-fault earthquakes shape memory alloy engineered cementitious composite self-centering